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Isolation and characterisation of a (-)-sparteine coordinated mixed alkyl/ amido sodium magnesiate, a chiral variant of an important utility ate base

Kennedy, A.R. and O'Hara, C.T. (2008) Isolation and characterisation of a (-)-sparteine coordinated mixed alkyl/ amido sodium magnesiate, a chiral variant of an important utility ate base. Dalton Transactions (37). pp. 4975-4977. ISSN 1472-7773

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Abstract

When a 1 : 1 (BuNa)-Bu-n-(Bu2Mg)-Bu-n,s mixture is treated with two molar equivalents of TMP(H) (TMP = 2,2,6,6-tetramethyl-piperidide) and one molar equivalent of (-)-sparteine in hydrocarbon medium, a new chiral mixed-metal, mixed alkylamide [{(-)-sparteine}center dot Na(mu-Bu)(mu-TMP)Mg(TMP)] can be isolated.

Item type: Article
ID code: 19499
Keywords: metal mediated magnesiation, deprotonation, manganation, lithiation, chemistry, reagents, diamines, Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
    Depositing user: Strathprints Administrator
    Date Deposited: 08 Jun 2010 10:31
    Last modified: 12 Mar 2012 11:12
    URI: http://strathprints.strath.ac.uk/id/eprint/19499

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