Kennedy, A.R. and O'Hara, C.T. (2008) Isolation and characterisation of a (-)-sparteine coordinated mixed alkyl/ amido sodium magnesiate, a chiral variant of an important utility ate base. Dalton Transactions (37). pp. 4975-4977. ISSN 1472-7773
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/b812085b
Abstract
When a 1 : 1 (BuNa)-Bu-n-(Bu2Mg)-Bu-n,s mixture is treated with two molar equivalents of TMP(H) (TMP = 2,2,6,6-tetramethyl-piperidide) and one molar equivalent of (-)-sparteine in hydrocarbon medium, a new chiral mixed-metal, mixed alkylamide [{(-)-sparteine}center dot Na(mu-Bu)(mu-TMP)Mg(TMP)] can be isolated.
| Item type: | Article |
|---|---|
| ID code: | 19499 |
| Keywords: | metal mediated magnesiation, deprotonation, manganation, lithiation, chemistry, reagents, diamines, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Strathprints Administrator |
| Date Deposited: | 08 Jun 2010 10:31 |
| Last modified: | 12 Mar 2012 11:12 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/19499 |
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