A concise route to difluorinated analogues of cyclitols and sugars

Kerouredan, E. and Percy, J.M. and Rinaudo, G. and Singh, K. (2008) A concise route to difluorinated analogues of cyclitols and sugars. Synthesis (24). pp. 3903-3918. ISSN 0039-7881

Abstract

Allyl ethers of trifluoroethanol are transformed to difluorinated analogues of deoxysugars via concise sequences involving dehydrofluorination/metallation, [3,3]-Claisen rearrangement, reduction, and RCM, affording cyclohexenediol substrates for dihydroxylation reactions.

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• Item metadata

  Item type:	Article
  ID code:	19338
  Dates:	Date Event 16 December 2008 Published
  Notes:	No contact email found.
  Subjects:	Science > Chemistry > Physical and theoretical chemistry
  Department:	Faculty of Science > Pure and Applied Chemistry
  Depositing user:	Strathprints Administrator
  Date deposited:	04 Jun 2010 13:09
  Last modified:	08 Apr 2024 17:44
  Related URLs:	Related item
  URI:	https://strathprints.strath.ac.uk/id/eprint/19338