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A concise route to difluorinated analogues of cyclitols and sugars

Kerouredan, E. and Percy, J.M. and Rinaudo, G. and Singh, K. (2008) A concise route to difluorinated analogues of cyclitols and sugars. Synthesis (24). pp. 3903-3918. ISSN 0039-7881

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Abstract

Allyl ethers of trifluoroethanol are transformed to difluorinated analogues of deoxysugars via concise sequences involving dehydrofluorination/metallation, [3,3]-Claisen rearrangement, reduction, and RCM, affording cyclohexenediol substrates for dihydroxylation reactions.

Item type: Article
ID code: 19338
Notes: No contact email found.
Keywords: carbasugars, cyclitols, difluorinated, metathesis, dihydroxylation, Physical and theoretical chemistry
Subjects: Science > Chemistry > Physical and theoretical chemistry
Department: Faculty of Science > Pure and Applied Chemistry
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Depositing user: Strathprints Administrator
Date Deposited: 04 Jun 2010 14:09
Last modified: 17 Jul 2013 00:46
URI: http://strathprints.strath.ac.uk/id/eprint/19338

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