Spicer, M.D. and Reglinski, J. (2009) Soft scorpionate ligands based on imidazole-2-thione donors. European Journal of Inorganic Chemistry (12). pp. 1553-1574. ISSN 1434-1948Full text not available in this repository. (Request a copy from the Strathclyde author)
This review describes the development. of the anionic soft scorpionate ligand hydrotris(methimazolyl)borate (Tm-Mc), its N-alkyl and N-aryl congeners and draws comparisons where appropriate with its close relatives, the dihydrobis(methimazolyl)borates (Bm(R)). Key features of the interaction of these species with metal centres, including bonding modes, electron-donor properties, M center dot center dot center dot H-B interactions, ligand degradation and metallaboratrane formation are addressed and a summary of the coordination chemistry of these species with both main (Foul) and transition metals is given.
|Keywords:||tripodal ligands, S ligands, scorpionate ligands, imidazole-2-thione, metal complexes, transition metals, coordination modes, Chemistry, Inorganic Chemistry|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Strathprints Administrator|
|Date Deposited:||23 May 2010 12:21|
|Last modified:||04 May 2016 16:01|