Spicer, M.D. and Reglinski, J. (2009) Soft scorpionate ligands based on imidazole-2-thione donors. European Journal of Inorganic Chemistry (12). pp. 1553-1574. ISSN 1434-1948
Full text not available in this repository. (Request a copy from the Strathclyde author)Abstract
This review describes the development. of the anionic soft scorpionate ligand hydrotris(methimazolyl)borate (Tm-Mc), its N-alkyl and N-aryl congeners and draws comparisons where appropriate with its close relatives, the dihydrobis(methimazolyl)borates (Bm(R)). Key features of the interaction of these species with metal centres, including bonding modes, electron-donor properties, M center dot center dot center dot H-B interactions, ligand degradation and metallaboratrane formation are addressed and a summary of the coordination chemistry of these species with both main (Foul) and transition metals is given.
| Item type: | Article |
|---|---|
| ID code: | 19164 |
| Keywords: | tripodal ligands, S ligands, scorpionate ligands, imidazole-2-thione, metal complexes, transition metals, coordination modes, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Strathprints Administrator |
| Date Deposited: | 23 May 2010 13:21 |
| Last modified: | 12 Mar 2012 11:12 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/19164 |
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