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Reactions of (-)-sparteine with alkali metal HMDS complexes : conventional meets the unconventional

Clark, N.M. and Garcia-Alvarez, P. and Kennedy, A.R. and O'Hara, C.T. and Robertson, G.M. (2009) Reactions of (-)-sparteine with alkali metal HMDS complexes : conventional meets the unconventional. Chemical Communications (London), 2009 (39). pp. 5835-5837. ISSN 0009-241X

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    Abstract

    Conventional (-)-sparteine adducts of lithium and sodium 1,1,1,3,3,3-hexamethyldisilazide (HMDS) were prepared and characterised, along with an unexpected and unconventional hydroxyl-incorporated sodium sodiate, [(-)-sparteine·Na(-HMDS)Na·(-)-sparteine]+[Na4(-HMDS)4(OH)]--the complex anion of which is the first inverse crown ether anion.

    Item type: Article
    ID code: 18948
    Keywords: (-)-sparteine, alkali metal, HMDS complexes, Chemistry, Chemistry(all)
    Subjects: Science > Chemistry
    Department: Faculty of Science > Pure and Applied Chemistry
    Related URLs:
      Depositing user: Strathprints Administrator
      Date Deposited: 21 Jun 2010 15:11
      Last modified: 28 Mar 2014 11:27
      URI: http://strathprints.strath.ac.uk/id/eprint/18948

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