Clegg, W. and Conway, B. and Garcia-Alvarez, P. and Kennedy, A.R. and Mulvey, R.E. and Russo, L. and Sassmannshausen, J. and Tuttle, Tell (2009) Structural tracking of the potassium-mediated magnesiation of anisole. Chemistry - A European Journal, 15 (41). pp. 10702-10706. ISSN 0947-6539
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1002/chem.200901897
Abstract
The potassium-mediated magnesiation of anisole has been monitored by a combination of X-ray crystallographic and NMR spectroscopic studies. Departing from a heteroleptic alkyl-amido base and anisole, the reaction first stops at an ortho-magnesiated anisole intermediate, but the final destination is an ortho-magnesiated anisole complex with reincorporation of the amine ligand and elimination of alkane (see picture).
| Item type: | Article |
|---|---|
| ID code: | 18896 |
| Keywords: | crystal structure, magnesiation, metalation, NMR spectroscopy, potassium, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Strathprints Administrator |
| Date Deposited: | 20 May 2010 14:59 |
| Last modified: | 12 Mar 2012 11:11 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/18896 |
Actions (login required)
| View Item |