Clegg, W. and Conway, B. and Garcia-Alvarez, P. and Kennedy, A.R. and Mulvey, R.E. and Russo, L. and Sassmannshausen, J. and Tuttle, Tell (2009) Structural tracking of the potassium-mediated magnesiation of anisole. Chemistry - A European Journal, 15 (41). pp. 10702-10706. ISSN 0947-6539Full text not available in this repository. (Request a copy from the Strathclyde author)
The potassium-mediated magnesiation of anisole has been monitored by a combination of X-ray crystallographic and NMR spectroscopic studies. Departing from a heteroleptic alkyl-amido base and anisole, the reaction first stops at an ortho-magnesiated anisole intermediate, but the final destination is an ortho-magnesiated anisole complex with reincorporation of the amine ligand and elimination of alkane (see picture).
|Keywords:||crystal structure, magnesiation, metalation, NMR spectroscopy, potassium, Chemistry, Chemistry(all)|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Strathprints Administrator|
|Date Deposited:||20 May 2010 13:59|
|Last modified:||27 Apr 2016 14:59|