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The decomposition of electrochemically loaded palladium hydride : a thermal analysis study

Berlouis, L.E.A. and Hall, P.J. and Mackinnon, A.J. and Wark, Alastair and Manuelli, D. and Gervais, V. and Robertson, J.E. (1997) The decomposition of electrochemically loaded palladium hydride : a thermal analysis study. Journal of Alloys and Compounds, 253-254. pp. 207-209. ISSN 0925-8388

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Abstract

Palladium samples electrochemically loaded with hydrogen have been examined in terms of their desorption characteristics using the thermal analysis methods of differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The temperature of maximum desorption is shown to depend on the H:Pd ratio n when loading was carried out at current densities iD≤2 mA cm−2. The molar desorption enthalpy ΔHM, derived from the DSC and TGA data as a function of n (0.48-0.9), was found to be in good agreement with literature values at lower n but deviated at higher n.

Item type: Article
ID code: 18344
Keywords: palladium, electrochemical loading, thermal desorption, Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Faculty of Engineering > Chemical and Process Engineering
Technology and Innovation Centre > Bionanotechnology
Related URLs:
    Depositing user: Strathprints Administrator
    Date Deposited: 24 Mar 2010 20:01
    Last modified: 09 Aug 2013 09:44
    URI: http://strathprints.strath.ac.uk/id/eprint/18344

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