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Strathprints serves world leading Open Access research by the University of Strathclyde, including research by the Strathclyde Institute of Pharmacy and Biomedical Sciences (SIPBS), where research centres such as the Industrial Biotechnology Innovation Centre (IBioIC), the Cancer Research UK Formulation Unit, SeaBioTech and the Centre for Biophotonics are based.

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Observation of first- and second-order transitions during the heating of Argonne Premium Coals

Mackinnon, A.J. and Hall, P.J. (1995) Observation of first- and second-order transitions during the heating of Argonne Premium Coals. Energy and Fuels, 9 (1). pp. 25-32. ISSN 0887-0624

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Abstract

Differential scanning calorimetry (DSC) has been used to investigate the thermal transitions occurring for a series of Argonne Premium Coals. Two sets of experiments were conducted using different heating profiles to further examine a Second-order transition which had previously been observed for Illinois No. 6 coal. Thermogravimetric analysis (TGA) was also conducted on the samples to support the DSC data. The DSC results show that on initial heating a first-order transition is observed which is a function of the cooling cycle and that subsequent scanning shows a clear and reproducible second-order process with the characteristics of a glass transition process. TGA shows that no mass loss, is associated with either of these transitions.