Norton, F.J. and Love, G.D. and Mackinnon, A.J. and Hall, P.J. (1995) Mechanisms of char production from oxidized cellulose. Journal of Materials Science, 30 (3). pp. 596-600. ISSN 0022-2461Full text not available in this repository. (Request a copy from the Strathclyde author)
A multi-technique approach, incorporating nuclear magnetic resonance (NMR), elemental analysis, differential scanning calorimetry (DSC), thermogravimetric analysis and surface area determination, has been used to investigate the formation of chars by oxidized cellulose. It was found that oxidation of the cellulose tends to increase the surface area of the resulting char. NMR, elemental analysis and DSC show how cellulose oxidation tends to increase aromaticity and cross-linking. This, in turn, decreases diffusion rates of volatiles out of the oxidized cellulose during pyrolysis, giving denser carbons and higher BET surface areas.
|Keywords:||carbon, wood, char, oxidized cellulose, Chemical engineering, Mechanics of Materials, Materials Science(all), Mechanical Engineering|
|Subjects:||Technology > Chemical engineering|
|Department:||Faculty of Engineering > Chemical and Process Engineering|
|Depositing user:||Strathprints Administrator|
|Date Deposited:||07 May 2010 09:59|
|Last modified:||27 Apr 2016 14:19|