Graham, D.V. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2006) Lithium dimethyl(amido)zinc complexes: contrasting zincate (amido = tmp) and inverse zincate (amido = hmds) structures on addition of TMEDA. Organometallics, 25 (14). pp. 3297-3300. ISSN 0276-7333
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1021/om060334i
Abstract
Introducing TMEDA to the lithium dimethyl(amido)zincates 'LiZn(NR2)Me2' leads to a discrete ion-contacted zincate with TMEDA bound to lithium in the case of NR2 = TMP but to a novel 'inverse zincate' with TMEDA bound to zinc in the case of NR2 = HMDS, where unexpectedly Me2Zn(TMEDA) functions as a η1,μ ligand to dimeric (LiHMDS)2 molecules to afford a zigzag chain polymer.
| Item type: | Article |
|---|---|
| ID code: | 17233 |
| Keywords: | TMEDA, lithium dimethyl(amido)zincates, LiZn(NR2)Me2, zincate, lithium, zinc, molecules, chain polymer, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Strathprints Administrator |
| Date Deposited: | 09 Apr 2010 12:18 |
| Last modified: | 12 Mar 2012 11:07 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/17233 |
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