Graham, D.V. and Hevia, E. and Kennedy, A.R. and Mulvey, R.E. (2006) Lithium dimethyl(amido)zinc complexes: contrasting zincate (amido = tmp) and inverse zincate (amido = hmds) structures on addition of TMEDA. Organometallics, 25 (14). pp. 3297-3300. ISSN 0276-7333Full text not available in this repository. (Request a copy from the Strathclyde author)
Introducing TMEDA to the lithium dimethyl(amido)zincates 'LiZn(NR2)Me2' leads to a discrete ion-contacted zincate with TMEDA bound to lithium in the case of NR2 = TMP but to a novel 'inverse zincate' with TMEDA bound to zinc in the case of NR2 = HMDS, where unexpectedly Me2Zn(TMEDA) functions as a η1,μ ligand to dimeric (LiHMDS)2 molecules to afford a zigzag chain polymer.
|Keywords:||TMEDA, lithium dimethyl(amido)zincates, LiZn(NR2)Me2, zincate, lithium, zinc, molecules, chain polymer, Chemistry, Organic Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Strathprints Administrator|
|Date Deposited:||09 Apr 2010 11:18|
|Last modified:||06 Jan 2017 07:29|