Strathprints Home | Open Access | Browse | Search | User area | Copyright | Help | Library Home | SUPrimo

A polymeric solvent-free variant of a hydridomagnesium inverse crown

Graham, D.V. and Kennedy, A.R. and Mulvey, R.E. and O'Hara, C.T. (2006) A polymeric solvent-free variant of a hydridomagnesium inverse crown. Acta Crystallographica Section C: Crystal Structure Communications, 62 (8). M366-M368. ISSN 0108-2701

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

A solvent-free agostically propagated polymeric variant of a previously reported hydride-containing inverse crown molecule has been prepared, namely tetra-mu(2)-diisopropylamido-di-mu(2)-hydrido-dimagnesium(II) disodium(I), [Mg2Na2H2(C6-H14N)(4)]. The asymmetric unit contains two crystallographically independent centrosymmetric molecules, each existing as a cationic eight-membered ring, with alternating metal and N atoms, which acts as a host towards two hydride anions. The metal amide rings are linked via Na (.) (.) (.) C agostic interactions to produce one-dimensional polymeric chains propagating along the crystallographic b direction.

Item type: Article
ID code: 17229
Keywords: alkali metal magnesium, chemistry, hydride, Chemistry, Biochemistry, Genetics and Molecular Biology(all)
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
    Depositing user: Strathprints Administrator
    Date Deposited: 07 Apr 2010 16:50
    Last modified: 05 Sep 2014 01:31
    URI: http://strathprints.strath.ac.uk/id/eprint/17229

    Actions (login required)

    View Item