Mills, A. and Tommons, Cheryl and Bailey, R.T. and Tedford, M.Catriona and Crilly, Peter J. (2007) Reversible, fluorescence-based optical sensor for hydrogen peroxide. Analyst, 132 (6). pp. 566-571. ISSN 0003-2654Full text not available in this repository. (Request a copy from the Strathclyde author)
The preparation and characterisation are described of a robust, reversible, hydrogen peroxide optical sensor, based on the fluorescent quenching of the dye ion-pair [Ru(bpy)32+(Ph4B-)2], by O2 produced by the catalytic breakdown of H2O2, utilizing the inorganic catalyst RuO2·xH2O. The main feature of this system is the one-pot formulation of a coating ink that, when dried, forms an active single-layer fluorescence-based H2O2 sensor, demonstrably capable of detecting H2O2 over the range of 0.01 to 1 M, with a relative standard deviation of ca. 4% and a calculated lower limit of detection of 0.1 mM. These sensors are sterilisable, using dry-heat, and stable when stored over 40 days, without exhibiting any loss in sensitivity or response characteristics.
|Keywords:||fluorescence-based optical sensor, hydrogen peroxide, optical sensor, dye, Chemistry, Biochemistry, Spectroscopy, Environmental Chemistry, Analytical Chemistry, Electrochemistry|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Strathprints Administrator|
|Date Deposited:||30 Apr 2010 10:22|
|Last modified:||27 Apr 2016 14:38|