Strathprints Home | Open Access | Browse | Search | User area | Copyright | Help | Library Home | SUPrimo

Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex

Carrella, L.M. and Clegg, William and Graham, D.V. and Hogg, L.M. and Kennedy, A.R. and Klett, J. and Mulvey, R.E. and Rentschler, E. (2007) Sodium-mediated manganation: direct mono- and dimanganation of benzene and synthesis of a transition-metal inverse-crown complex. Angewandte Chemie, 46 (25). pp. 4662-4666. ISSN 0044-8249

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

Inside out approach: Twofold deprotonation of benzene by a sodium monoalkyl bisamido manganate(II) reagent derived from BuNa, 2,2,6,6-tetramethylpiperidine, and Mn(CH2SiMe3)2 has produced the first inverse-crown complex in which the transition-metal atoms are incorporated in the host (see X-ray structure, blue N, green Na, purple Mn). Variable-temperature magnetization measurements show that the complex is antiferromagnetic.

Item type: Article
ID code: 17161
Notes: Strathprints' policy is to record up to 8 authors per publication, plus any additional authors based at the University of Strathclyde. More authors may be listed on the official publication than appear in the Strathprints' record.
Keywords: alkali metals, arenes, inverse-crown compounds, manganese, metalation, Chemistry, Medicine(all)
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
    Depositing user: Strathprints Administrator
    Date Deposited: 27 Apr 2010 16:45
    Last modified: 28 Mar 2014 05:15
    URI: http://strathprints.strath.ac.uk/id/eprint/17161

    Actions (login required)

    View Item