Conway, B. and Hevia, E. and Garcia-Alvarez, J. and Graham, D.V. and Kennedy, A.R. and Mulvey, R.E. (2007) Isolation and structural elucidation of a key aluminoaromatic intermediate and evidence for dismutation phenomena in tmp-alumination chemistry. Chemical Communications (London) (48). pp. 5241-5243. ISSN 0009-241X
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/b713913f
Abstract
Lithium TMP-aluminate iBu3Al(TMP)Li undergoes dismutation in THF solution to precipitate the tetraalkylaluminate [{Li·(THF)4}+{Al(iBu)4}-], but reacts kinetically as a TMP base towards N,N-diisopropylbenzamide to afford the crystalline ortho-aluminated species [(THF)3·Li{O(C)N(iPr)2(C6H4)}Al(iBu)3] and TMPH.
| Item type: | Article |
|---|---|
| ID code: | 17124 |
| Keywords: | dismutation, Lithium TMP-aluminate, Tetraalkylaluminate, crystalline ortho-aluminated species, aluminoaromatic intermediate, TMP-alumination chemistry, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Strathprints Administrator |
| Date Deposited: | 17 Apr 2010 12:50 |
| Last modified: | 04 Oct 2012 13:00 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/17124 |
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