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Synthesis and structure of the li-13 cage [{[o - p(mu-(nbu)-bu-t)](2)li-2}(3)(licl)(6)li(cl/(obu)-bu-n)(0.5)(thf)(7)], containing a [o - p(mu-(nbu)-bu-t)](2)(2-) dianion

Chan, W.T.K. and Eisler, D. and Garcia, F. and Gonzalez-Calera, S. and McPartlin, M. and Morey, J.V. and Mulvey, R.E. and Singh, S. (2008) Synthesis and structure of the li-13 cage [{[o - p(mu-(nbu)-bu-t)](2)li-2}(3)(licl)(6)li(cl/(obu)-bu-n)(0.5)(thf)(7)], containing a [o - p(mu-(nbu)-bu-t)](2)(2-) dianion. Chemical Communications (London) (19). pp. 2251-2253. ISSN 0009-241X

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Abstract

The hydrolysis of [ClP(-NtBu)]2 with H2O-Et3N in thf, followed by in situ lithiation with nBuLi gives the Li13 cage [{[OP(-NtBu)]2Li2}3(LiCl)6Li(Cl/OnBu)0.5(thf)7], containing a [OP(-NtBu)]22- dianion that is isoelectronic with ligands of the type [(RN)P(-NR)]22-. (Abstract edited from: http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=b800051d)

Item type: Article
ID code: 17077
Notes: Strathprints' policy is to record up to 8 authors per publication, plus any additional authors based at the University of Strathclyde. More authors may be listed on the official publication than appear in the Strathprints' record. http://suprimo.lib.strath.ac.uk/primo_library/libweb/action/display.do?ct=display&doc=SUVOY165400&indx=2&frbg=&dum=true&vid=SUVU01&vl(54032236UI0)=lsr02&vl(96071691UI1)=all_items&srt=rank&indx=1&dstmp=1272377732984&tab=local&ct=search&scp.scps=scope%3A(SU)&vl(freeText0)=Chemical%20Communications&fn=search&mode=Basic&dscnt=0
Keywords: RING-OPENING REACTIONS, CRYSTAL-STRUCTURES, TETRAHYDROFURAN, COMPLEXES, COORDINATION, MACROCYCLES, GUEST, LITHIATION, SELECTION, NITROGEN, Chemistry, Physical and theoretical chemistry, Chemistry(all)
Subjects: Science > Chemistry
Science > Chemistry > Physical and theoretical chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
    Depositing user: Strathprints Administrator
    Date Deposited: 27 Apr 2010 15:22
    Last modified: 05 Sep 2014 02:20
    URI: http://strathprints.strath.ac.uk/id/eprint/17077

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