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The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by University of Strathclyde researchers, including by researchers from the Department of Computer & Information Sciences involved in mathematically structured programming, similarity and metric search, computer security, software systems, combinatronics and digital health.

The Department also includes the iSchool Research Group, which performs leading research into socio-technical phenomena and topics such as information retrieval and information seeking behaviour.

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Synthesis and structure of the li-13 cage [{[o - p(mu-(nbu)-bu-t)](2)li-2}(3)(licl)(6)li(cl/(obu)-bu-n)(0.5)(thf)(7)], containing a [o - p(mu-(nbu)-bu-t)](2)(2-) dianion

Chan, W.T.K. and Eisler, D. and Garcia, F. and Gonzalez-Calera, S. and McPartlin, M. and Morey, J.V. and Mulvey, R.E. and Singh, S. (2008) Synthesis and structure of the li-13 cage [{[o - p(mu-(nbu)-bu-t)](2)li-2}(3)(licl)(6)li(cl/(obu)-bu-n)(0.5)(thf)(7)], containing a [o - p(mu-(nbu)-bu-t)](2)(2-) dianion. Chemical Communications (London) (19). pp. 2251-2253. ISSN 0009-241X

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Abstract

The hydrolysis of [ClP(-NtBu)]2 with H2O-Et3N in thf, followed by in situ lithiation with nBuLi gives the Li13 cage [{[OP(-NtBu)]2Li2}3(LiCl)6Li(Cl/OnBu)0.5(thf)7], containing a [OP(-NtBu)]22- dianion that is isoelectronic with ligands of the type [(RN)P(-NR)]22-. (Abstract edited from: http://www.rsc.org/Publishing/Journals/CC/article.asp?doi=b800051d)