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Effect of shear rate on aggregate size and morphology investigated under turbulent conditions in stirred tank

Soos, Miroslav and Moussa, Amgad S. and Ehrl, Lyonel and Sefcik, Jan and Wu, Hua and Morbidelli, Massimo (2008) Effect of shear rate on aggregate size and morphology investigated under turbulent conditions in stirred tank. Journal of Colloid and Interface Science, 319 (2). pp. 577-589. ISSN 0021-9797

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Aggregation and breakage of aggregates produced from fully destabilized polystyrene latex particles in turbulent flow was studied experimentally in both batch and continuous stirred tank. Detailed investigation of the initial kinetics showed that the collision efficiency, alpha, depends on the shear rate G according to alpha proportional to G(-b), with a power law exponent, b, equal to 0.18. After steady state was reached the dynamic response of the system on a change in stirring speed and solid volume fraction was investigated. It was found that the steady-state values of two measured moments of the cluster mass distribution (CMD) are fully reversible upon a change in stirring speed. This indicates that although the moments of CMD at steady-state depend on the applied shear rate, the aggregate structure is independent of the shear rate in the given range of stirring speeds. This was proved by independent measurement of the fractal dimension, d(f), using image analysis which provided a df equal to 2.62 +/- 0.18 independent of applied stirring speed. The critical aggregate size, below which breakage is negligible, determined by dilution experiments was consequently used to evaluate the aggregate cohesive force holding the aggregate together, which was found to be independent of the aggregate size and equal to 6.2 +/- 1.0 nN.

Item type: Article
ID code: 15032
Keywords: aggregation, breakage, turbulent conditions, polystyrene particles, shear rate effect, solid volume fraction effect, aggregation efficiency, steady-state reversibility, aggregate morphology, light scattering, image analysis, aggregate cohesive force, Chemical engineering, Biomaterials, Surfaces, Coatings and Films, Colloid and Surface Chemistry, Electronic, Optical and Magnetic Materials
Subjects: Technology > Chemical engineering
Department: Faculty of Engineering > Chemical and Process Engineering
Depositing user: Dr Jan Sefcik
Date Deposited: 29 Jan 2010 15:27
Last modified: 10 Dec 2015 18:11
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