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Self-sustaining smoldering combustion : a novel remediation process for non-aqueous-phase liquids in porous media

Switzer, C. and Pironi, P. and Gerhard, J.I. and Rein, G. and Torero, J.L. (2009) Self-sustaining smoldering combustion : a novel remediation process for non-aqueous-phase liquids in porous media. Environmental Science and Technology, 43 (15). pp. 5871-5877. ISSN 0013-936X

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Abstract

Smoldering combustion, the slow burning process associated typically with porous solids (e.g., charcoal), is here proposed as a novel remediation approach for nonaqueous phase liquids (NAPLs) embedded in porous media. Several one-dimensional vertical smoldering experiments are conducted on quartz sand containing fresh coal tar at an initial concentration of 71 000 mg/kg (approximately 25% saturation) and employing an upward darcy air flux of 4.25 cm/s. Following a short-duration energy input to achieve ignition at the lower boundary, a self-sustaining combustion front is observed to propagate upward at 1.3 × 10−2 cm/s. The process is self-sustaining because the energy released during NAPL smoldering is efficiently trapped and recirculated by the soil matrix, preheating the NAPL ahead of the reaction front. The smoldering process is observed to self-terminate when all of the NAPL is destroyed or when the oxygen source is removed. Pre- and post-soil analysis revealed that NAPL smoldering reduced the concentration of total extractable petroleum hydrocarbons (TPH) from 38 000 mg/kg to below detection limits (<0.1 mg/kg) throughout the majority of the column. A comparable experiment in which conductive heating is applied in the absence of smoldering demonstrates a 6-fold reduction in the net energy in the system and residual TPH values of 2000−35 000 mg/kg. A further repeat in which the air supply is prematurely terminated demonstrated that the NAPL smoldering process can be extinguished via external control. A suite of 23 demonstration experiments shows that NAPL smoldering is successful across a range of soil types (including simple layered systems) and contaminants (including laboratory mixtures of dodecane, DCA/grease, TCE/oil, vegetable oil, crude oil, and mineral oil) as well as field-obtained samples of materials containing coal tar, oil drill cutting waste, and oil sands.

Item type: Article
ID code: 13581
Notes: This paper introduced the concept of in situ smouldering for the remediation of hazardous organic liquids contaminants in the top international environmental journal. A proof of concept experiment was explored in significant detail to demonstrate in situ smouldering as a remediation process. The reviewers gave the manuscript scores of 8.5/10 for overall importance and 9.5/10 for originality or novelty of the work: “Subsurface DNAPL contamination is a multi-billion dollar problem which has proven to be a very difficult technological challenge to remediate. This proposed process… is like no other existing technology and constitutes the first "new" approach in many years.”
Keywords: smoldering combustion, combustion, civil engineering, remediation process, non-aqueous-phase liquids, porous media, Chemical technology, Environmental technology. Sanitary engineering, Engineering (General). Civil engineering (General)
Subjects: Technology > Chemical technology
Technology > Environmental technology. Sanitary engineering
Technology > Engineering (General). Civil engineering (General)
Department: Faculty of Engineering > Civil and Environmental Engineering
Related URLs:
    Depositing user: Dr Christine Switzer
    Date Deposited: 01 Dec 2009 17:12
    Last modified: 16 Jan 2013 11:26
    URI: http://strathprints.strath.ac.uk/id/eprint/13581

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