Picture of scraped petri dish

Scrape below the surface of Strathprints...

The Strathprints institutional repository is a digital archive of University of Strathclyde research outputs. Explore world class Open Access research by researchers at Strathclyde, a leading technological university.

Explore

Hysteretic adsorption and desorption of hydrogen by nanoporous metal-organic frameworks

Zhao, X.B. and Xiao, B. and Fletcher, A.J. and Thomas, K.M. and Bradshaw, D. and Rosseinsky, M.J. (2004) Hysteretic adsorption and desorption of hydrogen by nanoporous metal-organic frameworks. Science, 306 (5698). pp. 1012-1015. ISSN 0036-8075

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

Adsorption and desorption of hydrogen from nanoporous materials, such as activated carbon, is usually fully reversible. We have prepared nanoporous metal-organic framework materials with flexible linkers in which the pore openings, as characterized in the static structures, appear to be too small to allow H2 to pass. We observe hysteresis in their adsorption and desorption kinetics above the supercritical temperature of H2 that reflects the dynamical opening of the "windows" between pores. This behavior would allow H2 to be adsorbed at high pressures but stored at lower pressures.