Picture of aircraft jet engine

Strathclyde research that powers aerospace engineering...

The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by University of Strathclyde researchers, including by Strathclyde researchers involved in aerospace engineering and from the Advanced Space Concepts Laboratory - but also other internationally significant research from within the Department of Mechanical & Aerospace Engineering. Discover why Strathclyde is powering international aerospace research...

Strathprints also exposes world leading research from the Faculties of Science, Engineering, Humanities & Social Sciences, and from the Strathclyde Business School.

Discover more...

Structure of trans-[Rh(PPh3)2(CO)(OH2)][ClO4].CH2Cl2

Cross, R.J. and Kennedy, A.R. and Manojlovic-Muir, L.J. (1993) Structure of trans-[Rh(PPh3)2(CO)(OH2)][ClO4].CH2Cl2. Acta Crystallographica Section C: Crystal Structure Communications, 49 (6). pp. 1146-1148. ISSN 0108-2701

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

In crystals of trans-aquacarbonylbis(triphenylphosphine) rhodium(I) perchlorate dichloromethane solvate, the cations and anions are linked through O---H..-O hydrogen bonds to form dimeric [Rh(PPha)2(CO)(OH2)]2[C104]2 units characterized by crystallographically imposed 6',. symmetry. The cationic complex displays a slightly distorted squareplanar geometry around the Rh atom. The water molecule coordinates: the Rh I centre at an Rh--O distance of 2.127 (4) A,.