Cross, R.J. and Kennedy, A.R. and Manojlovic-Muir, L.J. (1993) Structure of trans-[Rh(PPh3)2(CO)(OH2)][ClO4].CH2Cl2. Acta Crystallographica Section C: Crystal Structure Communications, 49 (6). pp. 1146-1148. ISSN 0108-2701
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1107/S0108270192012666
Abstract
In crystals of trans-aquacarbonylbis(triphenylphosphine) rhodium(I) perchlorate dichloromethane solvate, the cations and anions are linked through O---H..-O hydrogen bonds to form dimeric [Rh(PPha)2(CO)(OH2)]2[C104]2 units characterized by crystallographically imposed 6',. symmetry. The cationic complex displays a slightly distorted squareplanar geometry around the Rh atom. The water molecule coordinates: the Rh I centre at an Rh--O distance of 2.127 (4) A,.
| Item type: | Article |
|---|---|
| ID code: | 1324 |
| Keywords: | crystals, dichloromethane solvate, crystallographically, geometry, cationic, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Catriona Mccallum |
| Date Deposited: | 28 Jun 2006 |
| Last modified: | 12 Mar 2012 10:36 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/1324 |
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