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trans-Bromo(o-tolyl)bis(triphenylphosphine)palladium(II) crystals with and without stacking faults

Cross, R.J. and Kennedy, A.R. and Muir, K.W. (1995) trans-Bromo(o-tolyl)bis(triphenylphosphine)palladium(II) crystals with and without stacking faults. Acta Crystallographica Section C: Crystal Structure Communications, 51 (2). pp. 208-210. ISSN 0108-2701

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Abstract

In trans-[PdBr(CTHT)(Cl8H15P)2] the Pd atom has almost regular square-planar coordination geometry; the length of the Pd--Br bond [2.517 (2),~.] indicates that the cr-tolyl group exerts a strong trans influence. The molecular structure obtained from an ordered crystal is indistinguishable from that derived from a crystal with a stacking fault.