Cross, R.J. and Kennedy, A.R. and Muir, K.W. (1995) trans-Bromo(o-tolyl)bis(triphenylphosphine)palladium(II) crystals with and without stacking faults. Acta Crystallographica Section C: Crystal Structure Communications, 51 (2). pp. 208-210. ISSN 0108-2701Full text not available in this repository. (Request a copy from the Strathclyde author)
In trans-[PdBr(CTHT)(Cl8H15P)2] the Pd atom has almost regular square-planar coordination geometry; the length of the Pd--Br bond [2.517 (2),~.] indicates that the cr-tolyl group exerts a strong trans influence. The molecular structure obtained from an ordered crystal is indistinguishable from that derived from a crystal with a stacking fault.
|Keywords:||Pd atom, cr-tolyl, crystal, geometry, Chemistry, Biochemistry, Genetics and Molecular Biology(all)|
|Subjects:||Science > Chemistry|
|Department:||Faculty of Science > Pure and Applied Chemistry|
|Depositing user:||Catriona Mccallum|
|Date Deposited:||28 Jun 2006|
|Last modified:||29 Apr 2016 00:04|