Kennedy, A.R. and Cross, R.J. and Muir, K.W. (1995) Preparation and crystal structure of trans-[NiBr{C6H3-2,6-(CH2PCy2)2}]. Inorganica Chimica Acta, 231 (1-2). pp. 195-200. ISSN 0020-1693
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1016/0020-1693(94)04321-L
Abstract
The synthesis of trans-[NiBr{C6H3-2,6-(CH2PCy2)2}], Cy = cyclohexyl, and its characterisation by spectroscopy and single crystal X-ray analysis are described. The constraints imposed by the bulky terdentate ligand lead only to minor distortions of the square planar nickel(II) coordination (P---Ni---P = 161.6(1)°). The nickel coordination is compared with those found in related complexes with terdentate N- and P-donor ligands.
| Item type: | Article |
|---|---|
| ID code: | 1320 |
| Keywords: | Crystal structures, Metallation, Nickel complexes, Organometallic complexes, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry |
| Related URLs: | |
| Depositing user: | Catriona Mccallum |
| Date Deposited: | 28 Jun 2006 |
| Last modified: | 04 Oct 2012 15:17 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/1320 |
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