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cis-Di(nitrato-O,O')bis(tricyclohexylphosphine oxide-O)nickel(II)

Kennedy, A.R. and Sloss, S.W. and Spicer, M.D. (1997) cis-Di(nitrato-O,O')bis(tricyclohexylphosphine oxide-O)nickel(II). Acta Crystallographica Section C: Crystal Structure Communications, 53 (3). pp. 292-294. ISSN 0108-2701

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Abstract

The formal pseudo-octahedral coordination around the Ni II atom in the title complex, [Ni(NO3)2(OPCy3)e], places the OPCy3 ligands (CI8H33OP; Cy is cyclohexyl, C6H11) in an unusual mutually cis conformation. This may be rationalized by viewing each bidentate NO3 group as occupying only one site of a tetrahedral coordination shell.