Strathprints logo
Strathprints Home | Open Access | Browse | Search | User area | Copyright | Help | Library Home | SUPrimo

Formation of the lithium alkylaluminium secondary amide [Me2Al{PhCH2}2Li.THF] by a methane elimination / amide insertion process

Armstrong, D.R. and Craig, F.J. and Kennedy, A.R. and Mulvey, R.E. (1998) Formation of the lithium alkylaluminium secondary amide [Me2Al{PhCH2}2Li.THF] by a methane elimination / amide insertion process. Journal of Organometallic Chemistry, 550 (1-2). pp. 355-358. ISSN 0022-328X

Full text not available in this repository. (Request a copy from the Strathclyde author)

Abstract

Synthesised by refluxing the amine adduct [Me3Al · (PhCH2)2NLi · HN(CH2Ph)2] in toluene/THF, the title compound has been structurally characterised by X-ray diffraction, and the methane elimination/amide insertion processes involved in its formation have been modelled theoretically through a series of ab initio MO calculations.

Item type: Article
ID code: 1300
Keywords: Ab initio, X-ray diffraction, Heterobimetallics, Aluminium, Amide, Lithium, Chemistry, Materials Chemistry, Biochemistry, Organic Chemistry, Physical and Theoretical Chemistry, Inorganic Chemistry
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
    Depositing user: Catriona Mccallum
    Date Deposited: 26 Jun 2006
    Last modified: 04 Sep 2014 10:02
    URI: http://strathprints.strath.ac.uk/id/eprint/1300

    Actions (login required)

    View Item