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A novel route to (+/-)-aspidospermidine: first application of 'radical-polar crossover' reactions to total synthesis

Callaghan, O. and Lampard, C. and Kennedy, A.R. and Murphy, J.A. (1999) A novel route to (+/-)-aspidospermidine: first application of 'radical-polar crossover' reactions to total synthesis. Tetrahedron Letters, 40 (1). pp. 161-164. ISSN 0040-4039

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Abstract

Aspidospermidine has been prepared by a novel route featuring TTF-induced cyclisation of a diazonium salt.