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A novel total synthesis of (+/-)-aspidospermidine

Callaghan, O. and Lampard, C. and Kennedy, A.R. and Murphy, J.A. (1999) A novel total synthesis of (+/-)-aspidospermidine. Journal of the Chemical Society, Perkin Transactions 1, 1999 (8). pp. 995-1002. ISSN 1472-7781

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Abstract

The tetrathiafulvalene-induced radical-polar crossover reaction has been applied to the total synthesis of the pentacyclic Aspidosperma alkaloid aspidospermidine.