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Diazadithiafulvalenes as electron donor reagents

Koizumi, T. and Bashir, N. and Kennedy, A.R. and Murphy, J.A. (1999) Diazadithiafulvalenes as electron donor reagents. Journal of the Chemical Society, Perkin Transactions 1, 1999 (24). pp. 3637-3643. ISSN 1472-7781

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Diazadithiafulvalenes act as excellent electron donors to arenediazonium salts. The diazadithiafulvalenium radical cations trap primary carbon radicals successfully. However, the diazadithiafulvalenium salts which form, undergo rapid ring fragmentation in contrast to their tetrathia counterparts.

Item type: Article
ID code: 1280
Keywords: Diazadithiafulvalenes, arenediazonium salts, tetrathia, Chemistry, Chemistry(all)
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Depositing user: Catriona Mccallum
Date Deposited: 23 Jun 2006
Last modified: 21 May 2015 08:08

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