Kennedy, A.R. and MacLellan, J.G. and Moir, J.H. and Mulvey, R.E. and Rodger, P.J.A. (2000) Synthesis of the mixed lithium-magnesium, mixed amide (R,R/S,S)-[{LiMg(TMP)[CH2Si(Me)(2)N(SiMe3)]}(2)]: a conformationally-locked structure of five fused rings inducing two stereogenic nitrogen centres. Chemical Communications (London), 2000 (18). pp. 1757-1758. ISSN 0009-241X
Full text not available in this repository. (Request a copy from the Strathclyde author)Official URL: http://dx.doi.org/10.1039/b004317f
Abstract
Reaction of the magnesium amide Mg(TMP)2 with the lithium amide LiHMDS is accompanied by an unexpected, sterically-promoted hydrogen transfer/amine elimination process, to yield the novel title compound which is the first such heterometallic composition to contain a heteroleptic amide ligand set.
| Item type: | Article |
|---|---|
| ID code: | 1270 |
| Keywords: | magnesium amide Mg(TMP)2, lithium amide LiHMDS, heterometallic composition, heteroleptic, Chemistry |
| Subjects: | Science > Chemistry |
| Department: | Faculty of Science > Pure and Applied Chemistry Unknown Department |
| Related URLs: | |
| Depositing user: | Catriona Mccallum |
| Date Deposited: | 23 Jun 2006 |
| Last modified: | 04 Oct 2012 15:18 |
| URI: | http://strathprints.strath.ac.uk/id/eprint/1270 |
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