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Preparation and crystal structure of the [bis{hydrotris(methimazolyl)borato}thallium(III)] cation: modulated chemistry resulting from the use of soft and hard tripodal ligands

Slavin, P.A. and Reglinski, J. and Spicer, M.D. and Kennedy, A.R. (2000) Preparation and crystal structure of the [bis{hydrotris(methimazolyl)borato}thallium(III)] cation: modulated chemistry resulting from the use of soft and hard tripodal ligands. Journal of the Chemical Society, Dalton Transactions, 2000 (3). pp. 239-240. ISSN 0300-9246

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Abstract

The synthesis and crystal structure of the [bis{hydrotris(methimazolyl)borato}thallium(III)] cation is reported, in which the thallium ion is co-ordinated by six sulfur thione donors in a regular octahedral environment.