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The Strathprints institutional repository is a digital archive of University of Strathclyde's Open Access research outputs. Strathprints provides access to thousands of Open Access research papers by Strathclyde researchers, including by researchers from the Physical Activity for Health Group based within the School of Psychological Sciences & Health. Research here seeks to better understand how and why physical activity improves health, gain a better understanding of the amount, intensity, and type of physical activity needed for health benefits, and evaluate the effect of interventions to promote physical activity.

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1,4-pentadienyl-3-sulfonamides: Frameworks for disfavored radical cascade cyclizations

Bommezijn, Sacha and Martin, Concepcion Gonzalez and Kennedy, Alan R. and Lizos, Dimitrios and Murphy, John A. (2001) 1,4-pentadienyl-3-sulfonamides: Frameworks for disfavored radical cascade cyclizations. Organic Letters, 3 (21). pp. 3405-3407. ISSN 1523-7060

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Abstract

1,4-Pentadienyl-3-sulfonamides afford products including those resulting from disfavored 5-endo-trig reactions when subjected to radical cyclization conditions. Products resulting from pathways featuring 4-exo-trig cyclizations are also detected, even when the 4-exo-trig reaction leads to a highly strained bicyclo[3.2.0] ring system.