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A mechanistic study of the ammonolysis of alkyl acetoacetates in water. Formation of 1,5-dimethyl-2,6,9- triazabicyclo[3.3.1]nonane-3,7-dione as the main product

Paredes, R. and Abonia, R. and Cadavid, J. and Moreno-Fuquen, Rodolfo and Jaramillo, A. and Hormaza, A. and Ramirez, A. and Kennedy, A.R. (2001) A mechanistic study of the ammonolysis of alkyl acetoacetates in water. Formation of 1,5-dimethyl-2,6,9- triazabicyclo[3.3.1]nonane-3,7-dione as the main product. Tetrahedron, 58 (1). pp. 55-60. ISSN 0040-4020

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Abstract

Ammonolysis of alkyl acetoacetates with 15% NH3 in water at room temperature initially lead to formation of alkyl β-aminocrotonates which slowly converted into 1,5-dimethyl-2,6,9-triaza-bicyclo[3.3.1]nonane-3,7-dione as the main product.

Item type: Article
ID code: 1128
Keywords: Ammonolysis, alkyl acetoacetates, temperature, aminocrotonates, Chemistry, Biochemistry, Organic Chemistry, Drug Discovery
Subjects: Science > Chemistry
Department: Faculty of Science > Pure and Applied Chemistry
Related URLs:
    Depositing user: Catriona Mccallum
    Date Deposited: 22 May 2006
    Last modified: 04 Sep 2014 10:54
    URI: http://strathprints.strath.ac.uk/id/eprint/1128

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